KE801: Inorganic Chemistry B (5 ECTS)

STADS: 10002801

Level
Master's level course

Teaching period
The course is offered in the spring semester.
4th quarter.

Teacher responsible
Email: ugn@ifk.sdu.dk

Timetable
Show entire timetable
Show personal time table for this course.

Prerequisites:
None

Academic preconditions:
KE524 quantum chemistry and KE525 inorganic chemistry (former KE512 quantum chemistry/inorganic chemistry) or KE818 Supplementary Course in Quantum Chemistry and Symmetry must be passed.

Course introduction
The aim of the course is to acquire knowledge about the structure of inorganic compounds, properties and reactions at an advanced level.

Expected learning outcome
At the end of the course the student is expected to master:

• assignments of electronic transitions in transition metal complexes
• calculations of magnetic moments in transition metal complexes.
• be able to suggest reasonable geometrical structures for transition metal complexes (including organometallic compounds).
• be able to suggest reaction mechanisms for the most important substitution and redox reactions involving transition metal complexes (including organometallic compounds).

Subject overview
Fundamental principles of the structure and reactivity of coordination compounds. Ligand field theory, interpretation of electronic spectra and magnetic properties of transition metal complexes. The mechanism of substitution and redox reactions. Organometallic chemistry including applications in catalysis. Selected topics from solid state chemistry. Synthesis and characterization of a series of inorganic compounds. The following methods will be used in the characterization:
UV-visible spectroscopy, NMR, Cyclic Voltammetry, Electron spin resonance (ESR). X-ray-diffraction.

Literature

• C. E. Housecroft & A. G. Sharpe: Inorganic Chemistry, Prentice Hall 3. Ed. Harlow 2008.
• Øvelsesvejledning til KE801.

Syllabus
See syllabus.

Website
This course uses e-learn (blackboard).

Prerequisites for participating in the exam
None

Assessment and marking:
a) Reports on lab exercises which evaluated collectively, passed/failed, internal censorship by lecturer. The candidate must have passed the reports to be able to participate in the written examination.
b) Two hours written examination graded according to the 7-point grading scale, external censorship.

Reexamination after 2nd quarter. The mode of exam at the reexamination may differ from the mode of exam at the ordinary exam.

Expected working hours
The teaching method is based on three phase model.

Forelæsninger, antal timer 20.
Eksaminatorietimer/opgaveregning, antal timer 10.
Laboratorieøvelser, antal timer 20.
Educational activities

Language
This course is taught in English, if international students participate. Otherwise the course is taught in Danish.

Course enrollment
See deadline of enrolment.

Tuition fees for single courses
See fees for single courses.